[1]李顺勇.氟橡胶包覆硝酸肼镍及其对雷管撞击感度的影响[J].365bet在线网址_365bet网上娱乐网址_365bet手机网址多少,2019,48(04):33-37.[doi:10.3969/j.issn.1001-8352.2019.04.006]
 LI Shunyong.Nickel Hydrazine Nitrate Coated with Fluororubber and Its Effect on Impact Sensitivity of Detonator[J].EXPLOSIVE MATERIALS,2019,48(04):33-37.[doi:10.3969/j.issn.1001-8352.2019.04.006]
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氟橡胶包覆硝酸肼镍及其对雷管撞击感度的影响()
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《365bet在线网址_365bet网上娱乐网址_365bet手机网址多少》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
48
期数:
2019年04
页码:
33-37
栏目:
爆炸材料
出版日期:
2019-07-04

文章信息/Info

Title:
Nickel Hydrazine Nitrate Coated with Fluororubber and Its Effect on Impact Sensitivity of Detonator
文章编号:
5333
作者:
李顺勇
保利久联控股集团九八四四生产分公司(贵州贵阳,550000)
Author(s):
LI Shunyong
9844 Production Branch, Poly Union Group Corporation (Guizhou Guiyang, 550000)
关键词:
硝酸肼镍;?氟橡胶;?包覆;?撞击感度
Keywords:
nickel hydrazine nitrate;? fluororubber;? coating;? impact sensitivity
分类号:
TJ45+5
DOI:
10.3969/j.issn.1001-8352.2019.04.006
文献标志码:
A
摘要:
利用水悬浮法将氟橡胶包覆在硝酸肼镍(NHN)表面制备出了NHN造型粉,并将其应用于基础雷管。通过DSC研究了NHN造型粉的热性能,测试了NHN造型粉的机械感度和火焰感度以及工业基础雷管的撞击感度和起爆能力。研究结果表明:氟橡胶包覆能够提高NHN的热稳定性,且热稳定性随着氟橡胶包覆量的增加而提高;NHN造型粉的机械感度均低于原料NHN,当氟橡胶包覆量(质量分数)为9%时,撞击感度下降幅度明显,可达142.9%;NHN造型粉用在基础雷管中做起爆药,可以降低基础雷管的撞击感度并保持其起爆能力。
Abstract:
Nickel hydrazine nitrate (NHN) molding powder, coating fluororubber on NHN surface, was prepared by water suspension method and applied in basic detonators. Thermal properties of molding powder were measured by DSC. Mechanical sensitivity and flame sensitivity of molding powder, as well as the impact sensitivity and initiation ability of basic detonators were tested. The results show that of NHN coated with fluorinerubber has enhanced thermal stability, which increases with the increasing of the fluorinerubber. Besides, the mechanical sensitivity of NHN molding powder is lower than that of raw NHN, and the impact sensitivity decreases by 142.9% when the mass fraction of fluorinerubber is 9%. Furthermore, NHN molding powder used as the primary explosive in detonator will reduce impact sensitivity and maintain initiation ability of basic detonator.

参考文献/References:

[1]艾鲁群.国外火工品手册(药剂和试验)[G].北京: 国家机械工业委员会兵器标准化研究所, 1988: 90-93.
[2]PATIL K, NESAMANI C, PAI VERNEKER V R . Synthesis and characterisation of metal hydrazine nitrate,azide and perchlorate complexes [J]. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 2006, 12(4): 383-395.
[3]ZHU S G, WU Y C, ZHANG W Y, et al. Evaluation of a new primary explosive: nickel hydrazine nitrate (NHN) complex [J]. Propellants, Explosives, Pyrotechnics, 1997,22(6): 317-320.
[4]王军.硝酸肼镍起爆药扩大应用[D].南京:南京理工大学,2008.
[5]杜伟兰,彭文林,聂祥进,等.以硝酸肼镍为基药的电点火头的制备及性能[J].365bet在线网址_365bet网上娱乐网址_365bet手机网址多少,2016,45(5):35-38.
DU W L, PENG W L, NIE X J,et al. Preparation and properties of a new electric fusehead based on nickel hydrazine nitrate [J]. Explosive Materials, 2016, 45(5):35-38.
[6]伍朝胜,何长见.硝酸肼镍含量测定方法探讨[J].365bet在线网址_365bet网上娱乐网址_365bet手机网址多少, 2009, 38(1): 26-27.
WU C S, HE C J. The discussion on the measurement of nickel hydrazine nitrate content [J]. Explosive Materials, 2009, 38(1): 26-27.
[7]乔羽,刘杰,肖磊,等.纳米RDX基PBX混合炸药的热分解特性和感度研究[J].365bet在线网址_365bet网上娱乐网址_365bet手机网址多少,2016,45(3):17-21.
QIAO Y,LIU J,XIAO L,et al.Study on thermal decomposition characteristics and sensitivities of nano-RDX based PBX[J]. Explosive Materials, 2016, 45(3): 17-21.
[8]吴娜娜,鲁志艳,金韶华,等. 水悬浮法制备NTO/HMX基PBX [J].现代化工,2016,36(3): 75-78.
WU N N, LU Z Y, JIN S H, et al. Preparation of NTO/HMX based PBX by water slurry method [J]. Modern Chemical Industry, 2016, 36(3): 75-78.
[9]陈健,王晶禹,王保国,等.水悬浮法制备ε-HNIW基传爆药的工艺研究[J].火炸药学报,2009,32(2):28-31.  
CHEN J, WANG J Y, WANG B G, et al. Study on preparation process of ε-HNIW booster explosive by water slurry method [J]. Chinese Journal of Explosive and Propellants,2009, 32(2): 28-31.
[10]王晶禹,高康,徐文峥,等.硬脂酸钙对CL-20/Estane复合粒子性能的影响[J].火炸药学报,2015,38(4): 22-26.  
WANG J Y, GAO K, XU W Z, et al. Effect of calcium stearate on the characteristics of CL-20/Estane composite particles [J]. Chinese Journal of Explosive and Propellants,2015, 38(4): 22-26.

相似文献/References:

[1]伍朝胜,何长见.硝酸肼镍含量测定方法探讨[J].365bet在线网址_365bet网上娱乐网址_365bet手机网址多少,2009,38(01):26.
 WU Chaosheng,HE changjian.The Discussion on the Measurement of Nickel Hydrazine Nitrate Content[J].EXPLOSIVE MATERIALS,2009,38(04):26.

备注/Memo

备注/Memo:
收稿日期:2019-01-28
第一作者:李顺勇(1981-),男,工程师,主要从事雷管的生产安全研究。E-mail:6870469844@qq.com
更新日期/Last Update: 2019-07-04